Chaotic Good are characters who are still considered heroic, but are free spirits who don't conform to law or order. Some chaotic good characters even downright hate these two things and think they do more harm than good.
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Sans
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Sam Manson
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Sam Stone
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Sanford
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Sanji
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Sarge (Red vs. Blue)
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Scarlet Witch
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Seras Victoria
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Shank
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Sharkboy
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Sheila
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Shouta Aizawa (Eraser Head)
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Shrek (DreamWorks)
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Slag (G1)
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Sludge (G1)
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Sly Cooper (character)
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Snarl (G1)
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Sol Badguy
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Sonic the Hedgehog (character)
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Sonic the Hedgehog (Paramount)
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Spear (Genndy Tartakovsky's Primal)
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Sprig Plantar
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Spyro (Legends)
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Squall Leonhart
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Stanley Pines
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Star-Lord
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Stitch
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Stripperella (character)
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Swindler
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Swoop (G1)